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A PETROGRAPHIC AND GEOCHEMICAL STUDY OFTHE POTTER MINE
AND INTERPRETATIONS ON IT'S VOLCANIC ENVIRONMENT
MUNRO TOWNSHIP, ONTARIO
FOR
MILLSTREAM MINES LTD.
BY
HAROLD GIBSON
SEPTEMBER 1998
SUMMARY
Appendix 1, to view Element Analyses on Potter
Core
Massive Cu, Zn, Co, Ag VMS mineralization at the Potter
mine occurs within a tholeiitic volcanic centre contained within a largely
ultramafic komatiitic volcanic succession. The mineralization is hosted
within a package of transported, basaltic hyaloclastite breccias and minor
sediments intruded by synvolcanic basaltic sills and dikes that occupy
a volcanic subsidence structure - basin or graben - on the flat, komatiitic
lava plain. The mineralization occurs as either massive to semi massive,
subseafloor replacement deposits within the hyaloclastite or as massive
sulphide lenses, associated with carbonaceous and argillaceous sediments,
that formed on the seafloor. The stacked, multi-lens nature of the mineralization
indicates that hydrothermal activity responsible for the mineralization
was active throughout, and interrupted
by, deposition or the hyaloclastite deposits. The semi-massive and massive
sulphide lenses are enveloped by an aerially restricted, semiconformable
black
chlorite alteration characterized by a depletion in SiO2, Na2O,
CaO and MgO and an enrichment in Fe2 O3 and metals.
The lack of an extensive, pervasive and/or discordant chlorite alteration
zone strongly suggests that the mineralization encountered is either a
product of a small, intermittent hydrothermal system or is fringe to a
larger system which may have formed a larger sulphide lens or lenses. The
mineralization is open at depth (along the plunge of the subsidence structure)
and to a lesser extent along strike, this coupled with its stacked character,
indicate that the potential for discovery of
additional
sulphide lenses is high.
RECOMMENDATIONS
l. Results of the orientation study indicate that lithogeochemistry
is useful in defining areas of altered chloritized-rock associated with
mineralization and in "finger-printing" the host stratigraphy which is
useful when tracing mineralization outside of the mine area and in the
resolution of structural problems. It is recommended that core from all
drill holes within and outside of the mine area be systematically sampled
for major elements plus Cu and Zn. Samples should be taken every 30m or
at a change in rock type and each sample should consist of
6-8,
2-4 cm long pieces taken over a 2 m interval. Major element data should
be examined visually and statistically arid plotted on plans and sections
where the data can be contoured. The orientation study suggests that oxides
such as Na2O, CaO, K2O, MgO and Fe2O3
may adequately define chlorite alteration
which is intimately associated with the mineralization. The immobile and
incompatible nature of Al2O3 and TiO2 make them useful
monitors of alteration and fractionation and removes the need to analyze
for expensive trace elements during "routine" exploration.
2. As recommended in a previous memo, all sulphide intersections
regardless of visible tenor or width should be assayed for Cu, Zn, Co,
Ag and Au. This new data, plus that generated from previous mining, should
be compiled onto sections and plans where the raw data for each element
and selected ratios (ex. Cu/Cu+Zn x 100; Cu x thickness etc..) are contoured.
Trends within the contoured data may indicate primary metal zoning variations
that can be tested by drilling. In particular, trends of Cu-enrichment
coupled with low Na2O and CaO and high MgO and Fe2O3
may
be particularly important in defining "core areas" within the paleohydrothermal
system which may be associated with larger and higher grade deposits.
3. A limited SEM study should be completed to: a) determine
the sulphide mineralogy, particularly how and where the Au, Ag and Co occur
in the sulphides (this may have metallurgical/recovery implications); b)
verify silicate mineralogy; and 3) quantify variations in alteration minerals
that may be useful in targeting mineralization (ie. Fe and metal content
of chlorite).
4. It may be worth while to examine the geology around
the Potterdoal mine as it appears to have a similar stratigraphic/structural
setting and it may provide some additional "clues" to controls on mineralization
at Potter.
A PETROGRAPHIC AND GEOCHEMICAL STUDY OF THE POTTER
MINE
AND INTERPRETATIONS ON IT'S VOLCANIC ENVIRONMENT
MUNRO TOWNSHIP, ONTARIO
FOR
MILLSTREAM MINES LTD.
INTRODUCTION
This report summarizes the results of a petrographic and
lithogeochemical study of the Potter mine host rocks and base metal mineralization
as represented in drill hole S97-9 (Figure I), as well as observations
of other drill core and surface exposures. Hole S97-9 was chosen on the
recommendation of Dave Gamble, Millstream Mines Consulting geologist, as
representative of the host rocks and mineralization. A total of 66 thin
sections were examined and 33 samples were analyzed for major and trace
elements (XRF-fused and pressed pellets) at the Central Analytical Laboratory,
Laurentian University. Samples were collected by Dave Gamble and myself
during an initial visit to the property in March and during a subsequent
visit in June. Samples were also collected to examine apparent silicification
of ultramafic footwall rocks (Table 3).
OBJECTIVES
The main objectives of this petrographic and geochemical
study were to: 1) describe and characterize the komatiitic and tholeiitic
host rocks, particularly the hyaloclastite units which host the base metal
mineralization; and 2) determine the alteration mineralogy and associated
compositional gains and losses. It was anticipated that results of the
study, and a summary of observations to date, would help to further characterize/clarify
the volcanic environment which hosts the Potter volcanic associated massive
sulphide (VMS) deposit and provide an orientation study for a more extensive
and systematic lithogeochemical sampling program designed to target/prioritize
areas for future drilling.
ORGANIZATION
The report is divided into three parts. The first part
is a description of the komatiitic and tholeiitic succession which contains
the mineralization as well as a discussion of its geochemical characteristics
(chemostratigraphy). The second part focuses on the base metal mineralization,
and the third part is a discussion of the alteration types recognized and
their geochemical signatures. Appendix I contains a table of geochemical
analyses (including those of Coad, 1976) as well as all geochemical diagrams
referred to in the text. Appendix II is a photographic atlas of thc various
rock and alteration types and, for documentation purposes, contains a least
one photomicrograph of each sample that was submitted for major and trace
element analysis.(Appendix II has been omitted from this particular copy
due to file size. Contact Millstream if interested.)
PART I: THE KOMATIITIC -THOLEIITIC VOLCANIC SUCCESSION
Potter mine (477,572 tonnes @ 1.67%
Cu; 1967-72), located within Munro Township, occurs within an east-southeast
trending Archean (2714 Ma) succession of mafic to ultramafic komatiitic
to tholeiitic volcanic and intrusive rocks referred to as Kidd-Munro Assemblage.
The Kidd-Munro Assemblage also hosts the world class Kidd Creek Cu-Zn-Ag
VMS deposit (> 138.7 million tonnes of 2.35%Cu, 6.50% Zn,
0.23% Pb and 89 g/t Ag) located some 80 kilometres to the east, near the
town of Timmins.
The Komatiitic -Tholeiitic volcanic succession which comprises
the Kidd-Munro Assemblage at the Potter mine is divisible into 3 lithostratigraphic
and chemostratigraphic units, which from oldest to youngest, includes:
1) a Lower ultramafic komatiite unit, 2) a Middle tholeiitic basalt unit;
and 3) an Upper ultramafic komatiite unit (Figure 1; Gamble, 1998). Basaltic
hyaloclastite of the Middle tholeiitic unit hosts mineralization at the
former Potter mine as well as mineralization encountered during the recent
deep drill programs which lies below the 8th underground level (1100 ft).
The Komatiitic-Tholeiitic volcanic succession strikes
east to east-southeast and dips steeply (85 deg.) to the north. The volcanic
succession faces north and is interpreted to lie on the south limb of a
west plunging regional synclinal structure whose fold axis lies north of
the mine (Coad, 1976; Gamble, 1998). Base metal mineralization at the former
Potterdoal mine is interpreted to lie on the north limb of this synclinal
structure and The Centre Hill Complex, a layered mafic-ultramafic tholeiitic
intrusion, which intrudes the Middle unit may be the stratigraphic equivalent
of Theo's flow or the Munro-Warden intrusive complex on the north limb
of the structure (Coad, 1976).
THE LOWER AND UPPER ULTRAMAFIC KOMATIITIC
The Lower and Upper komatiitic units, as well as Komatiitic
flows within the Middle tholeiitic unit, are described together as they
consist of massive periodititic and spinifex-textured flows. Spinifex-textured
flows are characterized by an upper chilled and polygonal fractured flow
top, an underlying spinifex zone and a base of massive pyroxene peridotite
as described for komatiitic flows at Pyke Hill, located east of the Potter
mine. These "layered" or "organized" spinifex flows are interpreted as
a distal or levee facies to more massive komatiitic flows that are interpreted
to represent a channelized facies (Hill et al., 1995 ). Spinifex texture
results from the parallel growth of large blade-like olivine crystals which
attain lengths of up to 2.5 cm, comprise up to 60% of the flow and are
invariably altered to serpentine (Plates 3,6,8,9,10 and 14). Skeletal crystals
of clinopyroxene are altered to fibrous amphibole arid locally massive
chlorite, presumably replacing original glass, occupies inter-olivine areas
(Plates 3,6,8,9,10 and 14). Samples of massive peridotite, either from
the base of spinifex flows or from massive, non-spinifex bearing flows
consist of closely packed, serpentinized, equant olivine crystals (up to
3mm in size) that comprise up to 80% (+) of the flow. The intercumulus
groundmass consists of acicular clinopyroxene altered to amphibole, with
massive chlorite presumably after original glass (Plates 1,2 arid 5 ).
Locally the intercumulate groundmass consists of subhedral clinopyroxene
(lesser orthopyroxene) crystals up to 3mm in diameter that poikilitically
enclose smaller equant crystals of serpentinized olivine (Plates 4,7,11,12
and 13).
The komatiitic affinity of both the massive and spinifex
texture flows is clearly indicated in Figures 2 and 3. The MgO content
of the flows range from 18 to 34 %, and the flows can be classified as
pyroxenitic and peridotitic komatiites. The spinifex textured flows typically
have a lower MgO content (<20 wt%) than the more massive flows (up to
34 wt%) as illustrated in Figure 4. Variations in Fe, Mg and Ca, as illustrated
in Figures 6,7,8, and 9, can be accounted for by olivine and lesser clinopyroxene
fractionation.
Paleoenvironment Interpretations
Komatiitic flows because of their low viscosity, a function
of high eruption temperature and composition, are interpreted to have constructed
extensive low relief lava plains (Hill et al., 1995). Flows
proximal to their vent they may have flowed turbulently and had a viscosity
akin to water and voluminous eruptions such as those responsible for the
Kidd-Munro Assemblage likely extended for a 100 or more kilometers from
their feeding fissure to essentially produce a broad lava plain analogous
to lava plains formed during flood-type basalt eruptions.
THE MIDDLE THOLEIITIC BASALT UNIT
The Middle Tholeiitic Basalt unit consists of hyaloclastite,
intact and autobrecciated sills (dikes) of massive quench-textured basalt,
thin discontinuous deposits of argillaceous and carbonaceous sediments,
chert, massive sulphide and komatiitic flows. The basalt sills and hyaloclastite
are identical in composition (Figure 5) and are chemically distinct from
the Upper and Lower komatiitic units as they have higher SiO2,
TiO2, Fe2O3 and lower MgO contents and
display a pronounced Fe-enrichment trend typical of tholeiites. Framework
supported units of densely packed, angular to subrounded fragments (<lmm
to 5mm) of altered basalt glass are referred to as hyaloclastite by Coad
(1976) and Gamble (1998). Certainly the blocky equant shape of the fragments,
the paucity of amygdules within the fragments and near ubiquitous perlitic
cracks supports an origin through passive quench fragmentation of basaltic
magma in contact with water and/or explosive hydrovolcanic eruptions. The
dominant fragment type is a grey-green coloured, chloritized aphyric basaltic
glass that is distinctly massive (Plates 16,19,20 22,23, and 37). Chloritized
sideromelane shards with relict palagonite rims and a more irregular morphology
arc also common (Plates 15,17,24,27,36,38,39). Fragments of olivine porphyritic
basalt, amygdaloidal aphyric basaIt and plagioclase microlitic basalt are
less common (Plate 22). Microslaggy textured (skeletal clinopyroxene needles)
basalt fragments described by Coad as the most dominant clast type were
not observed in the samples examined. Accessory fragments of chert, black
carbonaceous mudstone, argillaceous mudstone, and massive sulphide are
common but account for <1% by volume of the breccia (Plate 17).
The matrix ,which rarely exceeds 20% by volume of the
hyaloclastite, consists of: 1) fine ash-sized grains of quartz, plagioclase
and carbon interpreted by Coad (1976) as tuff; 2) coarse carbonate (dominant
matrix observed; Plate 37; 3) broken crystals of quartz, plagioclase and
pyroxene (Plates 23 and 26); 4) fine, massive chlorite (Plate 39); 5) black
carbonaceous sediment (Plate 44); and 6) massive sulphide (Plates 41).
Whether derived through either passive and/or explosive fragmentation of
basaltic magma the hyaloclastite deposits represent resedimented, syneruptive
deposits. Evidence in favour of this interpretation includes:
1) distinct bedding, although not apparent in surface
exposures; bedding defined by variations in clast size and matrix content
are well displayed in drill core; 2) good size
sorting; 3) near ubiquitous occurrence of argillaceous mudstone clasts
and occasional sulphide clasts (indicates mineralization, in part, was
emplaced during deposition of the hyaloclastite unit); 4) rounding of hyaloclastite
grains and granules; 5) occasional "felsic" clasts"; 6) interbedded argillaceous
mudstone beds (source of argillaceous and carbonaceous mudstone clasts);
and 7) absence of and gradational contact with, massive autobrecciated
basalt flows typical of proximal, primary hyaloclastite. A more accurate
term for this unit is "resedimented hyaloclastite" or the non-genetic "volcaniclastic
deposit", alternatively the terms volcanic sandstone and granule conglomerate
stress the resedimented character of the deposit.
Sills (and perhaps dikes) of massive and autobrecciated
basalt intrude hyaloclastite, mineralized hyaloclastite, massive sulphide
and argillaceous and carbonaceous mudstone. The basalt sills exhibit a
distinct quench texture characterized by equant, serpentinized olivine
microphenocrysts that sit in a groundmass of randomly orientated skeletal
clinopyroxetie (variably altered to amphibole/chlorite) occasionally intergrown
with skeletal plagioclase, and fine grained massive chlorite presumably
after devitrified glass (Plates 18,25,31 and 35). Coad (1976) referred
to this texture as a "microslaggy", typified his Broken Pillow Breccia
and Quench-textured Tholeiitic units.
The basalt sills are interpreted as high level, synvolcanic
intrusions emplaced into wet, unconsolidated hyaloclastite and sediment.
Evidenced for this interpretation includes: 1) their fractured and autobrecciated
upper and lower contacts with massive hyaloclastite, massive sulphide and
or argillite injected along fractures that penetrate the massive sill interior;
2) locally chilled and sharp upper and lower contacts; and 3) the development
of hyaloclastite along chilled and perlitic textured sill contacts and
the mixing of this hyaloclastite with enclosing argillaceous mudstones
and sulphide to form peperitic breccia - typical of subsurface magma/wet
sediment interaction (Plates 30 and 34). Hyaloclastite developed at the
margins of the basalt sills differs from the surrounding transported hyaloclastite
in that the former are invariably perlitic textured, are typically angular
and locally have delicate wispy forms displaying relict palagonite textured
margins. Where sills are in contact with carbonaceous sediments or massive
sulphide autobrecciation and quench fragmentation of the sill margins result
in the formation of "mixed" zones where massive intact globules of basalt
and hyaloclastite intimately mix with carbonaceous sediment to form a perperite
breccia (Plates 28 ,29 ,32,ancl 34 ).
The obvious textural and mineralogical similarity along
with identical chemical composition as illustrated in Figure 5 between
the basalt sills and Coad's Broken Pillow Breccia and Quench-texture Tholeiitic
units suggests that they are the same. The Broken Pillow Breccia arid Quench-Textured
Tholeiitic units observed by Coad at surface are now interpreted as autobrecciated
and intact, massive tholeiitic basalt sills respectively.
Paleoenvironment Interpretations
The hyaloclastite deposits may have been derived by quench
fragmentation and autobrecciation of basalt flows, however the lack of
larger lapilli and block-sized clasts of basalt, and the shear volume of
hyaloclastite does not support this interpretation. Instead, the production
of large volumes of lapilli-size hyaloclastite granules may best be explained
by quench fragmentation within a subaqueous lava fountain where the rapid
eruption of low viscosity magma into a water column resulted in localized
lava fountains where the magma was literally torn apart by rapid and quench-fragmented
to produce hyaloclastite. This mechanism of magma fragmentation has been
proposed by Smith and Batiza (1989) to explain hyaloclastite deposits (hyaloclastite
sands) on deep water seamounts. Irregardless of their origin the hyaloclastite
units were probably transported from their vent area(s) as high particle
concentration mass or grain flows and redeposited in a paleotopographic
depression within the underlying komatiitic flow topography. Assuming that
the komatiitic lava plain topography was essentially flat or horizontal
the paleotopographic depressions were likely fault controlled and may have
formed during subsidence of the volcanic pile during the tholeiitic volcanism.
The basalt sills and dikes may represent the last aliquot of tholeiitic
magma that was emplaced into hyaloclastite presumably along the same synvolcanic
structures that accommodated subsidence?
Thin, discontinuous deposits of argillaceous and carbonaceous
sediment and chert within the hyaloclastite deposits signify breaks in
hyaloclastite deposition that were dominated by fine suspension sedimentation
and hydrothermal discharge (chert, sulphides). Clasts of these sediments
within the hyaloclastite deposits probably represent rip-tips from underlying
sediments that may have been completely removed during emplacement of subsequent
mass/grain flows. The occurrence of massive sulphide clasts indicates that
hydrothermal discharge and sulphide deposition occurred during breaks in
hyaloclastite deposition, although the majority of the sulphide may have
formed below the seafloor within the hyaloclastite deposits as discussed
below.
The origin of carbon within the sediments, and as a matrix
to the hyaloclastite is unknown. It could be organic, or alternatively,
it could be the product of the reduction of magmatic CO2, a
common volatile associated with mafic volcanism.
The Centre Hill Complex
The Centre Hill Complex is a large differentiated peridotite-gabbro
sill-like (?) intrusion that has a strike length of approximately 1 km
and ranges up to 400m in thickness. It may be correlatable with the Munro-Warden
intrusive complex located on the north limb of the synclinal axis. The
Centre Hill Complex consists of a layered ultramafic (peridotite/pyroxenite)
base and an upper gabbroic part, up to 200m thick, that intrudes tholeiitic
hyaloclastite and sills of the overlying volcanic succession (Coad, 1976).
The gabbro has a subophitic texture characterized by subhedral clinopyroxene
intersticial to plagioclase laths with an interstitial groundmass of finer
plagioclase, clinopyroxene, quartz and chlorite (Plate 46). The Centre
Hill Complex is significant in that it was interpreted by Coad (1976) to
be a high-level synvolcanic intrusion emplaced into its own volcanic pile,
an interpretation supported by its compositional similarity to tholeiitic
sills and hyaloclastite. It essentially defines a tholeiitic volcanic centre
and, as such, is important in volcanic reconstruction.
Volcanic centres are typically characterized by subsidence
and the formation of fault controlled topographic depressions or basins
such as the basin or graben inferred to have localized the hyaloclastite
deposits at the Potter mine. They are also areas of high heat flow and
cross-stratal permeability which are requirements for the generation of
a high temperature, seawater dominated hydrothermal system that may account
for the alteration observed within the volcanic pile, and perhaps the sulphide
deposits themselves.
PART II. BASE METAL MINERALIZATION
Two basic types of base metal sulphide mineralization
are recognized, subseafloor sulphide and seafloor sulphide. In both types
the predominant sulphide is pyrrhotite with lesser sphalerite and chalcopyrite.
Subseafloor sulphide consists of disseminated and semi-massive sulphide
mineralization (10-80% sulphides) which occurs within the matrix to hyaloclastite.
Mineralization ranges from disseminated sulphide, often replacing an earlier
carbonate cement (Plate 45), to semi-massive sulphide where black, chloritized,
wispy hyaloclastite shards sit in a massive sulphide matrix (Plates 40
and 41). The delicate wispy nature of the chloritized hyaloclastite shards
within semi massive sulphide lenses is not a primary feature but a product
of their replacement along shard margins and perlitic cracks (Plates 42
and 43). Thus, the hyaloclastite host acted as a trap for sulphide mineralization
and the lenses grew through processes of cementation and replacement where
metals were trapped and not dispersed via plumes into the water column.
Subseafloor replacement is a mechanism common, but not restricted to, the
formation of many large massive sulphide deposits. Lenses of subseafloor
sulphide are interpreted to have grown by the precipitation of sulphides
within the permeable hyaloclastite matrix and by replacement of the matrix
and, to some extent, the hyaloclastite shards.
Seafloor sulphide consists of massive sulphide lenses
that are devoid of hyaloclastite and range from a few decimeters to metres
thick. They are typically associated with argillaceous or carbonaceous
mudstone beds (Plate 33). These massive sulphide lenses are interpreted
to have formed by exhalative activity on the seafloor during hiatuses in
hyaloclastite deposition marked by the deposition of argillaceous sediments.
Alternatively, the massive sulphide lenses may have formed below and within
argillaceous mudstones that acted as an aquiclude. Sulphide clasts within
the hyaloclastite unit are interpreted to have been derived from seafloor
sulphide deposits.
Paleoenvironment Interpretations
Without a doubt hydrothermal activity responsible for
the formation of massive sulphide deposits at and below the seafloor occurred
throughout the depositional history of the hyaloclastite units. This implies
a relatively long-lived, sustained hydrothermal event which favours the
formation of numerous stratigraphically stacked sulphide deposits. Although
textural and field evidence is limited to a few cross-cutting relationships
it is tentatively interpreted that early formed massive and banded pyrrhotite
and sphalerite is replaced by chalcopyrite. This paragenetic sequence is
typical of many VMS deposits, and by analogy, may reflect original temperature
gradients and sequential replacement during formation of thc sulphide lenses
where an early, "lower temperature" pyrrhotite/sphalerite mineralization
was progressively replaced by "higher temperature" chalcopyrite.
PART III. ALTERATION
The typical "alteration assemblages" recognized within
mafic and ultramafic rocks of the Potter volcanic succession could be ascribed
to hydration during regional greenschist facies metamorphism. Regional
metamorphism can result in the pseudomorphic replacement of olivine and
clinopyroxene by serpentine and amphibole/chlorite respectively, and the
replacement of glass, both within the flows and hyaloclastite, by chlorite,
amphibole and minor quartz. These mineralogical changes are not textually
destructive and can generally be assumed to have been isochemical. A quick
glance at the analysis in Tables 1 and 2 indicate compositions that are
typical, for the most part, of least altered flows.
There is, however, evidence of hydrothermal alteration
and this is best displayed within the hyaloclastite shards which record
a complex alteration history that is not always apparent in the flows.
A tentative paragenetic sequence for alteration of the glass shards is
as follows:
1) Initial palagonitization, which resulted in the development
of both fibrous and gel palagonite on any free surface in contact with
water such as shard boundaries or perlitic cracks (Plate 27). Palagonitization
is a low temperature alteration (<150°C) that result in the hydration
of glass, oxidation of Fe to form minute oxide granules which define palagonite
textures in older rocks and, possibly, minimal removal of SiO2 or
MgO from the glass. In most cases palagonitization
is assumed to be isochemical.
2) Chloritization, which resulted in the replacement of
glass shards and palagonite by chlorite (+/- amphibole, quartz) overprints
palagonitization. Chlorite may be a synvolcanic alteration, a result of
complete hydration of the glass during diagenesis/spilitization or it could
be a product of later greenschist facies metamorphism. In either case it
is not textually destructive as even the delicate textures of former palagonite
are preserved. Chlorite alteration may or may not be accompanied by spilitization
which results in the removal of Ca and addition of Na. Na2O
values >3.0 wt%, such as in samples S97-9-342.1,-368.1, -569.5 and
S98-2-357.5, may be a product of spilitization that accompanied an early,
synvolcanic regional chlorite alteration.
3) Carbonate alteration, which is more common in the ultramafic
flows but is also present in the basalt sills and hyaloclastite, appears
to overgrow serpentine, pyroxene and chlorite which suggests that it may
be syn- to post-greenschist facies metamorphism. Carbonate cement, a common
matrix to the hyaloclastite breccias, represents an earlier synvolcanic,
hydrothermal event. Whether or not any of the carbonate found within the
flows and sills is a product of this earlier carbonate event is uncertain.
4) Black chlorite alteration which resulted in the replacement
of shards by chlorite (Fe-rich chlorite?) and the destruction of former
palagonite textures is the alteration type which is spatially associated
with the sulphide mineralization (Plates 40 to 43). Black chlorite alteration
is most evident in the core where the hyaloclastite shards take on a distinct
black colouration , as opposed to their normal green-grey colour, immediately
adjacent (within decimeters to meters) to massive and semi-massive sulphide.
Assuming constant TiO2 mass balance calculations indicate that
black chlorite alteration is accompanied by a loss of SiO2,
CaO, Na2O and MgO and an addition of Fe2O 3
(Table
3). Some of the Fe2O3 enrichment is attributable
to matrix sulphide. These chemical changes and textures are typical of
chlorite alteration associated with VMS deposits.
Interpretations
Palagonitization, early chloritization/spilitization and,
to some extent carbonitization, are all typical of regional semi-conformable
alteration zones found in most VMS districts (Noranda, Mattagami, Snow
Lake, Sturgeon Lake....). They typically occur in the footwall, but also
the hanging wall, to VMS deposits. They are interpreted to be a product
of large scale, regional hydrothermal systems akin to modern day geothermal
fields. Their genetic relationship, if any, to base metal deposits
is uncertain, however they are an indicator of large hydrothermal systems
which are a key requisite for the formation of VMS deposits.
The black chlorite alteration is typical of chlorite alteration
zones that typify proximal discordant, and often pipe-like footwall, and
to a lesser extent hanging wall, alteration zones to VMS deposits, such
as those in the Noranda Camp. The chlorite is interpreted to be the product
of high temperature fluid rock interaction within discordant, structurally
controlled, fluid discharge channelways that acted as the principal conduits
for ascending hydrothermal fluids which formed massive sulphide deposits
at and below the seafloor. The restricted distribution and apparently semiconformable
character of black chlorite alteration at Potter is not typical of proximal;
discordant chlorite alteration zones and may suggest a more fringe or distal
environment
Appendix 1, to view Element Analyses on Potter
Core
REFERENCES
Arndt, N.T., 1976. Ultramafic rocks of Munro Township
and their volcanic setting. Unpublished PhD thesis, Univ. Of Toronto.
Coad, P.R., 1976. The Potter Mine. Unpublished
Msc thesis, Univ. Of Toronto.
Hill, RET., Barnes, S.J., Gole, M.J. And Dowling, S.E.,
1995. Thc volcanology of komatiites as deduced from field relationships
in the Norseman-Wiluna greenstone belt, Western Australia. Lithos, v.34,
p.1-25.
Jensen, L.S., 1976. A new cation plot for classifying
subalkalic volcanic rocks. Ontario Div. of Mines Misc. Publication 62.
Smith, T.L., and Batiza, K., 1989. New field and laboratory
evidence for the origin of hyaloclastite flows on seamount summits. Bull
of Volcanology, V.51, p. 96-114.
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